The effect of shear‐thickening on the stability of slot‐die coating. Issue 12 (9th June 2016)

• Record Type: Journal Article
• Authors: Khandavalli, Sunilkumar; Rothstein, Jonathan P.
• Is Part Of: AIChE journal. Volume 62:Issue 12(2016)
• Page Start: 4536
• Page End: 4547
• Publication Date: 2016-06-09
• Subjects: slot die -- coating -- shear thickening -- shear thinning -- colloids -- extensional rheology -- operating window -- ribbing; Chemical engineering -- Periodicals; Génie chimique -- Périodiques; 660.28
• DOI: 10.1002/aic.15336
• Languages: English
• ISSNs: 0001-1541

Abstract

Abstract : Slot‐die coating is an economical roll‐to‐roll processing technique with potential to revolutionize the fabrication of nano‐patterned thin films at high throughput. In this study, the impact of shear‐thickening of the coating fluid on the stability of slot‐die coating was investigated. For the coating fluid, a model system fumed silica nanoparticles dispersed in polypropylene glycol was chosen. These dispersions exhibit shear and extensional thickening characterized through steady shear and capillary break‐up measurements. The critical web velocity for the onset of coating defect for different flow rates was measured, while the type of coating defect was visualized using a high speed camera. For the shear thickening particle dispersions, the coating failed through the onset of a ribbing instability. The critical web velocity for the onset of coating defect was found to decrease with increasing particle concentration and increasing fluid viscosity. The minimum wet thickness was studied as a function of capillary number for the particle dispersions and compared with a series of Newtonian fluids with similar viscosities. In all cases, shear‐thickening behavior was found to stabilize coating by reducing the minimum wet coating thickness when compared against a Newtonian fluid with similar viscosity at the same capillary number. Conversely, the shear‐thinning fluids tested destabilized the coating by increasing the minimum wet thickness when compared against a Newtonian at the same capillary number. The impact of shear‐thickening on slot‐die coating was further studied by quantifying the evolution of the ribbing instability with increasing web speed and by conducting tests over a wide range of coating gaps. © 2016 American Institute of Chemical Engineers AIChE J, 62: 4536–4547, 2016