Indium-mediated cleavage of the trityl group from protected alcohols and diols. Issue 49 (8th December 2016)
- Record Type:
- Journal Article
- Title:
- Indium-mediated cleavage of the trityl group from protected alcohols and diols. Issue 49 (8th December 2016)
- Main Title:
- Indium-mediated cleavage of the trityl group from protected alcohols and diols
- Authors:
- Behloul, Cherif
Chouti, Aicha
Guijarro, David
Foubelo, Francisco
Nájera, Carmen
Yus, Miguel - Abstract:
- Abstract: The reaction of primary, secondary, allylic and benzylic trityl ethers with indium powder in MeOH/NH4 Cl led to reductive cleavage of the trityl-oxygen bond, affording the corresponding alcohols in good to excellent yield under very mild reaction conditions. The detritylation process could successfully be extended to mono and detritylated diols. This methodology represents a new and efficient detritylation procedure under mild reaction conditions. Graphical abstract:
- Is Part Of:
- Tetrahedron. Volume 72:Issue 49(2016)
- Journal:
- Tetrahedron
- Issue:
- Volume 72:Issue 49(2016)
- Issue Display:
- Volume 72, Issue 49 (2016)
- Year:
- 2016
- Volume:
- 72
- Issue:
- 49
- Issue Sort Value:
- 2016-0072-0049-0000
- Page Start:
- 7937
- Page End:
- 7941
- Publication Date:
- 2016-12-08
- Subjects:
- Indium -- Detritylation -- Trityl ethers -- Protected alcohols -- Protected diols
Chemistry, Organic -- Periodicals
547.005 - Journal URLs:
- http://www.elsevier.com/journals ↗
- DOI:
- 10.1016/j.tet.2016.10.020 ↗
- Languages:
- English
- ISSNs:
- 0040-4020
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 8796.850000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 594.xml