Anaerobic digestion of recalcitrant textile dyeing sludge with alternative pretreatment strategies. (December 2016) - Xiang, Xinyi
Graphical abstract: Highlights: AD of recalcitrant TDS were investigated after applying diverse pretreatments. Thermal alkaline pretreated TDS dramatically solubilised. Thermal pretreated TDS surprisingly showed highest methane production. Rate-limiting steps in AD of TDS were slow hydrolysis rate and inhibited acidogenesis. Dewaterability of TDS could be improved by disintegration of dyes contained. Abstract: Abundant organic compounds in textile dyeing sludge (TDS) provide possibility for its anaerobic digestion (AD) treatment. However, preliminary test showed little biogas generation in direct AD of the TDS during 20 days. In order to improve the AD availability of TDS, alkaline, acid, thermal and thermal alkaline pretreatments were performed. Color and aromatic amines were specifically measured as extra characteristics for the AD of TDS. The rate-limiting steps of AD of TDS were slow hydrolysis rate and inhibited acidogenesis, which were somewhat overcome by pretreatments. Thermal alkaline pretreated TDS performed best enhancement on solubilisation. The biochemical methane potential tests revealed that thermal pretreated TDS showed highest total methane production of 55.9 mL/g VSfed compared to the control with little methane generation. However, thermal alkaline pretreated TDS did not perform well in BMP test as expected. Moreover, the hydrophilicity of reactive dyes in TDS could seriously affect dewaterability of TDS.