Silica nanoparticle-embedded urethane acrylate nanohybrid thermosets for photo-patternable transparent hard coating. (22nd November 2016)

• Record Type: Journal Article
• Authors: Kang, Dong Jun; Park, Go Un; Im, Hyeon-Gyun; Park, Hoy Yul; Jin, Jungho
• Is Part Of: Polymer. Volume 105(2016)
• Page Start: 19
• Page End: 24
• Publication Date: 2016-11-22
• Subjects: Urethane-acrylate -- Silica nanoparticles -- Organic/inorganic hybrid; Polymers -- Periodicals; Polymerization -- Periodicals; Polymères -- Périodiques; Polymérisation -- Périodiques; 547.7
• DOI: 10.1016/j.polymer.2016.10.008
• Languages: English
• ISSNs: 0032-3861

Abstract

Abstract: Here, we report on the synthesis of a silica nanoparticle (SNP)-embedded urethane acrylate (UA) nanohybrid material (SNP-UA) and demonstrate its performance as photo-patternable transparent hard coating for optical applications. The SNP (10–20 nm) were synthesized via a base-catalyzed sol-gel condensation and the surface of SNP was chemically modified with methyl and methacryl organic functions by simple and mild solution processes, which not only enabled complete dispersion of SNP in the UA matrix but also rendered chemically cross-linked hybrid network of the SNP-UA. As an UV-curable optical hard coating, the SNP-UA exhibited excellent optical transparency coupled with a tunability of refractive index, good anti-scratch performance, and photo-patternability. Graphical abstract: Highlights: Synthesis of a silica nanoparticle (SNP)-embedded urethane acrylate (UA) nanohybrid material (SNP-UA). Chemically modified SNP enabled complete dispersion of SNP in the UA matrix and also rendered chemically cross-linked hybrid network of the SNP-UA.