Polyethylene terephthalate degradation under reactor neutron irradiation. (January 2017)

• Record Type: Journal Article
• Authors: Chikaoui, K.; Izerrouken, M.; Djebara, M.; Abdesselam, M.
• Is Part Of: Radiation physics and chemistry. Volume 130(2017)
• Page Start: 431
• Page End: 435
• Publication Date: 2017-01
• Subjects: Polyethylene terephthalate -- Reactor neutron irradiation -- Fast neutron -- UV–vis -- FTIR -- XRD; Radiation chemistry -- Periodicals; Radiometry -- Periodicals; Radiation -- Periodicals; Chimie sous rayonnement -- Périodiques; 539.2
• DOI: 10.1016/j.radphyschem.2016.10.002
• Languages: English
• ISSNs: 0969-806X

Abstract

Abstract: This paper is devoted to study the defects generated by reactor neutron in polyethylene terephthalate (PET) films. The explored fast neutron fluence ranges from 2.02×10 16 to 2.07×10 18 n cm −2 . The induced damages were investigated using ultraviolet-visible spectrophotometry (UV-vis), Fourier Transform Infrared spectrometry (FTIR) and X-ray diffraction (XRD). The UV-vis spectra show important changes indicating the degradation of the chemical structure and the creation of new chromophores. FTIR spectra reveal that the intensities of the different absorption bands decrease linearly under fast neutron irradiation. The internal reference band at 1410 cm −1 is used to follow the overall damage during irradiation. The 1342 cm −1 band corresponding to CH2 wagging of trans conformation of crystalline phase show a sharpe linear decrease as the fast neutrons fluence goes up. The creation of the monosubstituted benzene, investigated using the 1610 cm −1 band. It shows a linear increase with fast neutron fluence. It is found from XRD analysis that the diffraction peak (100) intensity is drastically reduced after irradiation at 2.02×10 16 n cm −2 . Highlights: We studied the degradation of PET polymeric material under reactor neutron environment. Optical and structural properties are progressively destroyed after irradiation. The band gap decreases linearly with the fast neutron fluence. The crystallinity is drastically reduced after irradiation to fast neutron fluence of 2.0×10 16 n/cm 2 . A linear relationship between the FTIR absorption band intensity and fast neutron fluence is observed.