A novel method to enhance silicon incorporation into nickel electrodeposited coatings. (December 2016)

• Record Type: Journal Article
• Authors: Alizadeh, Morteza; Teymuri, Alireza; Salahinejad, Erfan; Alijani, Fatemeh
• Is Part Of: Vacuum. Volume 134(2016)
• Page Start: 103
• Page End: 109
• Publication Date: 2016-12
• Subjects: Composite coatings -- Milling -- Electrodeposition -- Microstructure; Vacuum -- Periodicals; 621.55
• DOI: 10.1016/j.vacuum.2016.10.006
• Languages: English
• ISSNs: 0042-207X

Abstract

Abstract: It is known that the addition of silicon to nickel coatings can advantageously improve the coatings' characteristics, especially oxidation resistance. However, the incorporation of Si, because of its relatively low electrical conductivity, into Ni-electrodeposited coatings hardly exceeds 1 wt %. In this work, a new method is pointed out to increase the introduction of Si into Ni-electrodeposited coatings. In this regard, Ni-Si composite coatings were deposited on low-carbon steel by nickel electrodeposition from Watt's baths with the different concentrations of treated and untreated silicon particles. The treated particles were prepared by simultaneous milling of silicon and nickel powders (in 80:20 wt ratio), while the untreated particles were obtained from milling of only silicon particles. The structural characteristics of the produces were studied by scanning electron microscopy, energy dispersive X-ray spectroscopy, and X-ray diffraction. As the most typical finding of the work, it was realized that by using the treated particles, the content of silicon in the deposited composite coating reaches about 9.5 wt %, although it does not exceed 1 wt % when using the untreated particles. Highlights: Ni-Si coating with high Si content was successfully produced by electrodeposition. XRD analysis showed the preparation of a nanostructured Ni-Si coating. No new phase was created during milling process of the Si/Ni powders after 21 h. Si content of the coating deposited by the treated particles reached to 9.5 wt %.