Adsorption properties of regenerative materials for removal of low concentration of toluene. (1st December 2016)

• Record Type: Journal Article
• Authors: Xie, Zhen-Zhen; Wang, Lin; Cheng, Ge; Shi, Lei; Zhang, Yi-Bo
• Is Part Of: Journal of the Air & Waste Management Association. Volume 66:Number 12(2016)
• Page Start: 1224
• Page End: 1236
• Publication Date: 2016-12-01
• Subjects: Air -- Pollution -- Periodicals; Air quality management -- Periodicals; Hazardous wastes -- Management -- Periodicals; Air Pollution -- prevention & control -- Periodicals; Hazardous Waste -- prevention & control -- Periodicals; Waste Management -- Periodicals; 628.5305
• DOI: 10.1080/10962247.2016.1209257
• Languages: English
• ISSNs: 1047-3289

Abstract

ABSTRACT: A specific type of material, activated carbon fiber (ACF), was modified by SiO2, and the final products ACF-x were obtained as ACF-12.5, ACF-20, ACF-40, and ACF-80 according to different dosages of tetraethoxysilane (TEOS). The modified material on the ACF surface had a significant and smooth cover layer with low content of silica from scanning electron microscope (SEM) image. The modified ACF-x showed the stronger hydrophobicity, thermal stability, and adsorption capacity, which had almost no effect in the presence of water vapor and no destruction in multiple cycles. ACF-20 was proven as the most efficient adsorbent in humid conditions. The dual-function system composed of the regenerative adsorbents and the combustion catalyst would be efficient in consecutive toluene adsorption/oxidation cycles, in which the combustion catalyst was prepared by the displacement reaction of H2 PtCl6 with foam Ni. Therefore, the adsorption/catalytic oxidation could be a promising technique in the indoor air purification, especially in the case of very low volatile organic compound (VOC; toluene) concentration levels. Implications : Exploring highly effective adsorptive materials with less expensive costs becomes an urgent issue in the indoor air protection. ACF-20 modified by SiO2 with Pt/Ni catalysts shows stronger hydrophobicity, thermal stability, and adsorption capacity. This dual-function system composed of the regenerative materials and the combustion catalyst would be a promising technique in the indoor air purification, especially in the case of removal of very low concentration of toluene.