Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes. (10th October 2016)
- Record Type:
- Journal Article
- Title:
- Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes. (10th October 2016)
- Main Title:
- Silyl Formates as Surrogates of Hydrosilanes and Their Application in the Transfer Hydrosilylation of Aldehydes
- Authors:
- Chauvier, Clément
Thuéry, Pierre
Cantat, Thibault - Abstract:
- Abstract: Silyl formates are investigated for the first time as surrogates of hydrosilanes. In the presence of a well‐defined ruthenium catalyst, these reagents are shown to promote the chemoselective reduction of a variety of aldehydes by transfer hydrosilylation. Mechanistic investigations have shown that genuine hydrosilane species are avoided during catalysis. The mechanism involves a sequence of decarboxylation/insertion/transmetallation steps.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 45(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 45(2016)
- Issue Display:
- Volume 128, Issue 45 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 45
- Issue Sort Value:
- 2016-0128-0045-0000
- Page Start:
- 14302
- Page End:
- 14306
- Publication Date:
- 2016-10-10
- Subjects:
- Dichtefunktionalrechnungen -- Hydrosilylierungen -- Reaktionsmechanismen -- Ruthenium -- Silane
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201607201 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 475.xml