High Gas Adsorption Capacity of an agw‐Type Metal–Organic Framework Decorated with Methyl Groups. Issue 29 (21st September 2016)

• Record Type: Journal Article
• Authors: Du, Liting; Lu, Zhiyong; Xu, Li; Ma, Mengtao; Zhang, Jinchi
• Is Part Of: European journal of inorganic chemistry. Issue 29(2016)
• Page Start: 4727
• Page End: 4730
• Publication Date: 2016-09-21
• Subjects: Metal–organic frameworks -- Solvothermal synthesis -- Carbon dioxide storage -- Adsorption -- Methylation; Chemistry, Inorganic -- Periodicals; Organometallic chemistry -- Periodicals; Bioinorganic chemistry -- Periodicals; Solid state chemistry -- Periodicals; 546
• DOI: 10.1002/ejic.201600576
• Languages: English
• ISSNs: 1434-1948

Abstract

Abstract : A new methyl‐functionalized metal–organic framework, {Cu3 (CMPEIP)2 · 2H2 O} n {m‐NB13, H3 CMPEIP = 5‐[(4‐carboxy‐2‐methylphenyl)ethynyl]isophthalic acid} was solvothermally synthesized and structurally characterized. {Cu3 (CMPEIP)2 · 2H2 O} n exhibits a high BET surface area of 3215.4 m 2 g –1, a large H2 uptake (1.92 wt.‐% at 0.1 MPa and 77 K), and excellent CO2 storage capacity (9.24 wt.‐% at 0.1 MPa and 298 K). Abstract : A new methyl‐functionalized metal–organic framework, {Cu3 (CMPEIP)2 · 2H2 O} n {m‐NB13, H3 CMPEIP = 5‐[(4‐carboxy‐2‐methylphenyl)ethynyl]isophthalic acid} is synthesized and characterized. {Cu3 (CMPEIP)2 · 2H2 O} n exhibits a high BET surface area of 3215.4 m 2 g –1, a large H2 uptake (1.92 wt.‐% at 0.1 MPa and 77 K), and excellent CO2 storage capacity (9.24 wt.‐% at 0.1 MPa and 298 K).