[2]Rotaxanes comprising a macrocylic Hamilton receptor obtained using active template synthesis: synthesis and guest complexation. Issue 9 (2nd October 2016)

• Record Type: Journal Article
• Authors: Tron, Arnaud; Thornton, Peter J.; Kauffmann, Brice; Tucker, James H. R.; McClenaghan, Nathan D.
• Is Part Of: Supramolecular chemistry. Volume 28:Issue 9/10(2016)
• Page Start: 733
• Page End: 741
• Publication Date: 2016-10-02
• Subjects: Rotaxane -- activate template synthesis -- Hamilton receptor -- macrocycle -- click chemistry; Macromolecules -- Periodicals; Supramolecular chemistry -- Periodicals; 547.005
• DOI: 10.1080/10610278.2015.1122194
• Languages: English
• ISSNs: 1061-0278

Abstract

Abstract: A macrocyclic ring comprising multiple hydrogen-bonding sites as well as metal-chelating sites is shown to play the role of ligand in active templated, copper-catalysed [2]rotaxane formation via Huisgen and Glaser reactions. The crystallographic structure and copper ion binding studies are provided for the free macrocycle, along with molecular modelling, barbital, N, N′-trimethyleneurea and copper (I) binding information for the new rotaxanes. Abstract :