First cage-like pentanuclear Co(ii)-silsesquioxane. Issue 35 (15th July 2016)

• Record Type: Journal Article
• Authors: Bilyachenko, A. N.; Yalymov, A. I.; Levitsky, M. M.; Korlyukov, A. A.; Es'kova, M. A.; Long, J.; Larionova, J.; Guari, Y.; Shul'pina, L. S.; Ikonnikov, N. S.; Trigub, A. L.; Zubavichus, Y. V.; Golub, I. E.; Shubina, E. S.; Shul'pin, G. B.
• Is Part Of: Dalton transactions. Volume 45:Issue 35(2016)
• Page Start: 13663
• Page End: 13666
• Publication Date: 2016-07-15
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt02026g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A new pentanuclear "cylinder"-like cobalt(ii ) phenylsilsesquioxane [(PhSiO1.5 )10 (CoO)5 (NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols. Abstract : A new pentanuclear "cylinder"-like cobalt(ii ) phenylsilsesquioxane [(PhSiO1.5 )10 (CoO)5 (NaOH)] exhibits a slow relaxation of the magnetization and a high catalytic activity and stereoselectivity in the oxidation of alkanes and alcohols.