Supramolecular structure of 5-methyl-5-phenyl hydantoin and hydrogen-bonding patterns in 5, 5′-substituted hydantoins. (12th April 2016)

• Record Type: Journal Article
• Authors: Delgado, G. E.; Rodríguez, J. A.; Mora, A. J.; Bruno-Colmenárez, J.; Uzcátegui, J.; Chacón, C.
• Is Part Of: Molecular crystals and liquid crystals. Volume 629(2016)
• Page Start: 96
• Page End: 104
• Publication Date: 2016-04-12
• Subjects: Hydantoin compounds -- crystal structure -- hydrogen-bond patterns; Molecular crystals -- Periodicals; Liquid crystals -- Periodicals; Liquid crystals; Molecular crystals; Periodicals; 548
• DOI: 10.1080/15421406.2015.1107745
• Languages: English
• ISSNs: 1542-1406

Abstract

ABSTRACT: The crystal structure of heterocyclic compound 5-methyl-5-phenyl hydantoin has been determined from X-ray single crystal structural characterization. This material crystallizes in the orthorhombic system and noncentrosymmetric space group P21 (N°4). The crystal packing is governed by N–H···O hydrogen bond-type intermolecular interactions, forming chains and edge-fused 12-membered rings with graph-set C(4) C(5) C22(8) R33(12) in a similar hydrogen-bonding pattern of another chiral 5, 5′-substituted hydantoins.