Biomass derived carbon nanoparticle as anodes for high performance sodium and lithium ion batteries. (August 2016)

• Record Type: Journal Article
• Authors: Gaddam, Rohit Ranganathan; Yang, Dongfang; Narayan, Ramanuj; Raju, KVSN; Kumar, Nanjundan Ashok; Zhao, X.S.
• Is Part Of: Nano energy. Volume 26(2016:Aug.)
• Page Start: 346
• Page End: 352
• Publication Date: 2016-08
• Subjects: Bio-mass carbon -- Anode -- Battery -- Sodium-ion -- Lithium-ion; Nanoscience -- Periodicals; Nanotechnology -- Periodicals; Nanostructured materials -- Periodicals; Power resources -- Technological innovations -- Periodicals; Nanoscience; Nanostructured materials; Nanotechnology; Power resources -- Technological innovations; Periodicals; 621.042
• DOI: 10.1016/j.nanoen.2016.05.047
• Languages: English
• ISSNs: 2211-2855

Abstract

Abstract: In this paper, we report a flame deposition method to prepare carbon nanoparticles (CNPs) from coconut oil. The CNPs were further modified with a piranha solution to obtain surface-carboxylated carbon nanoparticles ( c -CNPs). When used as an anode for sodium-ion batteries, the CNPs and c -CNPs respectively delivered discharge capacities of 277 and 278 mA h g −1 in the second cycle at a current density of 100 mA g −1 . At the 20th cycle, the capacities of CNP and c-CNPs were 217 and 206 mA h g −1 respectively. The results suggest that modification of the CNPs with the piranha solution improved neither the charge storage capacity nor the stability against cycling in a sodium-ion battery. When the CNP and c -CNP were used an anode in a lithium-ion battery, 2nd-cycle discharge capacities of 741 and 742 mA h g −1 respectively at a current density of 100 mA g −1 were obtained. After 20 cycles the capacities of CNP and c -CNP became 464 and 577 mA h g −1 respectively, showing the cycling stability of the CNPs was improved after modification. The excellent cycling performance, high capacity and good rate capability make the present material as highly promising anodes for both sodium-ion and lithium-ion batteries. Graphical abstract: Carbon nanoparticles derived from biomass and their electrochemical performance as anode in both sodium-ion and lithium-ion batteries. Highlights: Carbon nanoparticles (CNPs) were prepared from biomass. CNPs work as a robust anode material with high discharge capacities for NIBs and LIBs. CNPs exhibited superior rate and cycling performance for both LIBs and NIBs.