Alkali activated construction materials: Assessing the alternative use for oil shale processing solid wastes. (30th September 2016)

• Record Type: Journal Article
• Authors: Paiste, Päärn; Liira, Martin; Heinmaa, Ivo; Vahur, Signe; Kirsimäe, Kalle
• Is Part Of: Construction & building materials. Volume 122(2016)
• Page Start: 458
• Page End: 464
• Publication Date: 2016-09-30
• Subjects: Oil shale -- Geopolymers -- Alkali-activated materials -- C-A-S-H gel -- Ambient curing; Building materials -- Periodicals; 624.18
• DOI: 10.1016/j.conbuildmat.2016.06.073
• Languages: English
• ISSNs: 0950-0618

Abstract

Highlights: Additional source of silicate is needed to achieve polymerization. Main reaction product responsible for structural strength is a C-(A)-S-H phase. Structure and formation of C-(A)-S-H phase is limited by reactive Ca bearing phases. C-(A)-S-H gel is predominantly a depolymerized one dimensional structure. Abstract: The potential of oil shale ash wastes as a source material for geopolymeric or alkali activated construction materials was assessed using structural, XRD, SEM, SEM-EDX, ATR-FTIR and 29 Si MAS-NMR methods. Fresh, unhydrated furnace bottom and cyclone separator ash along ash plateau sediment were used in combination with 5 M NaOH and Na2 SiO3 solutions with SiO2 /Na2 O ratios of 2.72 and 1.5 as alkaline activators, under ambient curing conditions. Our analytical results show that only activator solutions containing soluble silicate will induce the formation of amorphous C-(A)-S-H gel, giving the samples 8 times higher compressive strength (8.5 MPa) than samples exhibiting cementitious properties upon hydration (1.25 MPa).