Highly active and stable Ni/Y2Zr2O7 catalysts for methane steam reforming: On the nature and effective preparation method of the pyrochlore support. (13th July 2016)

• Record Type: Journal Article
• Authors: Fang, Xiuzhong; Zhang, Xianhua; Guo, Yao; Chen, Mengmeng; Liu, Wenming; Xu, Xianglan; Peng, Honggen; Gao, Zhixian; Wang, Xiang; Li, Changqing
• Is Part Of: International journal of hydrogen energy. Volume 41:Number 26(2016)
• Page Start: 11141
• Page End: 11153
• Publication Date: 2016-07-13
• Subjects: Pyrochlore support -- Glycine-nitrate combustion -- Coke resistance -- Methane steam reforming -- Supported Ni catalysts; Hydrogen as fuel -- Periodicals; Hydrogène (Combustible) -- Périodiques; Hydrogen as fuel; Periodicals; 665.81
• DOI: 10.1016/j.ijhydene.2016.04.038
• Languages: English
• ISSNs: 0360-3199

Abstract

Abstract: In this study, Y2 Zr2 O7 pyrochlore supports were synthesized by co-precipitation (Y2 Zr2 O7 -CP), glycine-nitrate combustion (Y2 Zr2 O7 -GNC) and hydrothermal (Y2 Zr2 O7 -HT) methods, which were used to support 10% Ni to prepare catalysts for methane steam reforming for hydrogen production. It is revealed that the three supports consist solely of pyrochlore phase, but have different morphologies, pore structures and surface areas. While Y2 Zr2 O7 -HT support possesses the highest surface area, Y2 Zr2 O7 -CP has the lowest one. As supports for Ni, H2 -TPR demonstrates that the Ni active species has stronger interaction with Y2 Zr2 O7 -GNC than with other two supports. Therefore, much smaller Ni crystallite sizes with higher metallic active surface area have been achieved. In addition, the surface of this catalyst is enriched with Ni species, as evidenced by the XPS results. As a consequence, Ni/Y2 Zr2 O7 -GNC exhibits the highest activity and stability, and the most potent coke resistance among all the catalysts, for which no evident coking and deactivation was observed even after testing at 800 °C under 20 atm for 200 h. It is concluded that the active metallic Ni surface area is the determining factor for the activity and coke-resistance of the catalyst. Graphical abstract: Highlights: Y2 Zr2 O7 pyrochlore supports were successfully synthesized by different methods. Ni has stronger interaction with a support prepared by glycine-nitrate combustion. Ni has higher active surface area and smaller crystallite size on this support. Hence Ni/Y2 Zr2 O7 -GNC exhibits superior activity and coke resistance. The support structures influence the reforming performance of the catalysts.