The new triazine-based porous copper phosphonate [Cu3(PPT)(H2O)3]·10H2O. Issue 8 (27th January 2015)

• Record Type: Journal Article
• Authors: Hermer, N.; Stock, N.
• Is Part Of: Dalton transactions. Volume 44:Issue 8(2015)
• Page Start: 3720
• Page End: 3723
• Publication Date: 2015-01-27
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c4dt03698k
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A new thermally stable copper phosphonate with pores of 9.4 Å diameter and a high water uptake at p / p 0 = 0.2 is described. Abstract : High throughput methods were employed in the discovery of [Cu3 (PPT)(H2 O)3 ]·10H2 O (denoted CAU-14). The structure contains one-dimensional channels with a diameter of 9.4 Å. Thermal activation leads to the formation of uncoordinated metal sites and a high water uptake of 39.1 wt% was found.