Bis-phosphine allene ligand: coordination chemistry and preliminary applications in catalysis12. Issue 41 (22nd April 2016)

• Record Type: Journal Article
• Authors: Vanitcha, Avassaya; Damelincourt, Cecilia; Gontard, Geoffrey; Vanthuyne, Nicolas; Mouriès-Mansuy, Virginie; Fensterbank, Louis
• Is Part Of: Chemical communications. Volume 52:Issue 41(2016)
• Page Start: 6785
• Page End: 6788
• Publication Date: 2016-04-22
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc02316a
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : A 1, 3-bis-diphenylphosphine allene provided new coordination complexes with palladium, platinum and gold salts. The dinuclear gold(i ) complex gave promising results in asymmetric catalysis. Abstract : A 1, 3-bis-diphenylphosphine allene can give rise to new coordination complexes with palladium, platinum and gold metals. These complexes were fully characterized by NMR, HRMS and X-ray diffraction analysis. For gold(i ), the corresponding dinuclear complex has been used in a series of diagnostic catalytic reactions and gave promising preliminary results in asymmetric catalysis.