Immobilization of ionic liquids to covalent organic frameworks for catalyzing the formylation of amines with CO2 and phenylsilane. Issue 44 (6th May 2016)

• Record Type: Journal Article
• Authors: Dong, Bin; Wang, Liangying; Zhao, Shang; Ge, Rile; Song, Xuedan; Wang, Yu; Gao, Yanan
• Is Part Of: Chemical communications. Volume 52:Issue 44(2016)
• Page Start: 7082
• Page End: 7085
• Publication Date: 2016-05-06
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc03058k
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : We presented the immobilization of ionic liquids on the channel walls of COFs using a post-synthetic strategy. Abstract : We presented the immobilization of ionic liquids on the channel walls of COFs using a post-synthetic strategy. The ionic [Et4 NBr]50% -Py-COF afforded a high CO2 adsorption capacity of 164.6 mg g −1 (1 bar, 273 K) and was developed as an effective heterogeneous catalyst for the transformation of CO2 into value-added formamides under ambient conditions.