Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative. Issue 44 (22nd April 2016)
- Record Type:
- Journal Article
- Title:
- Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative. Issue 44 (22nd April 2016)
- Main Title:
- Expanding the phosphorus–carbon analogy: formation of an unprecedented 5-phosphasemibullvalene derivative
- Authors:
- Rigo, Massimo
Weber, Manuela
Müller, Christian - Abstract:
- Abstract : The selective and quantitative photochemical di-π-methane rearrangement of a phosphabarrelene allows access to the first 5-phosphasemibullvalene derivative. Abstract : We could access for the first time a 5-phosphasemibullvalene derivative via quantitative and selective photochemical di-π-methane rearrangement from the corresponding phosphabarrelene. Due to the striking analogy between phosphorus and carbon, this hitherto unknown transformation of vinyl-phosphorus species provides the possibility to prepare novel, chiral and conformationally rigid organophosphorus cage compounds in a straightforward manner.
- Is Part Of:
- Chemical communications. Volume 52:Issue 44(2016)
- Journal:
- Chemical communications
- Issue:
- Volume 52:Issue 44(2016)
- Issue Display:
- Volume 52, Issue 44 (2016)
- Year:
- 2016
- Volume:
- 52
- Issue:
- 44
- Issue Sort Value:
- 2016-0052-0044-0000
- Page Start:
- 7090
- Page End:
- 7093
- Publication Date:
- 2016-04-22
- Subjects:
- Chemistry -- Periodicals
540 - Journal URLs:
- http://pubs.rsc.org/en/journals/journalissues/cc ↗
http://www.rsc.org/ ↗ - DOI:
- 10.1039/c6cc02461k ↗
- Languages:
- English
- ISSNs:
- 1359-7345
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 3139.350000
British Library DSC - BLDSS-3PM
British Library STI - ELD Digital store - Ingest File:
- 1897.xml