Adsorption of two gas molecules at a single metal site in a metal–organic framework. Issue 53 (10th June 2016)

• Record Type: Journal Article
• Authors: Runčevski, Tomče; Kapelewski, Matthew T.; Torres-Gavosto, Rodolfo M.; Tarver, Jacob D.; Brown, Craig M.; Long, Jeffrey R.
• Is Part Of: Chemical communications. Volume 52:Issue 53(2016)
• Page Start: 8251
• Page End: 8254
• Publication Date: 2016-06-10
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc02494g
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : One strategy to markedly increase the gas storage capacity of metal–organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Abstract : One strategy to markedly increase the gas storage capacity of metal–organic frameworks is to introduce coordinatively-unsaturated metal centers capable of binding multiple gas molecules. Herein, we provide an initial demonstration that a single metal site within a framework can support the terminal coordination of two gas molecules—specifically hydrogen, methane, or carbon dioxide.