Composition-dependent metallic glass alloys correlate atomic mobility with collective glass surface dynamics. Issue 25 (10th June 2016)

• Record Type: Journal Article
• Authors: Nguyen, Duc; Zhu, Zhi-Guang; Pringle, Brian; Lyding, Joseph; Wang, Wei-Hua; Gruebele, Martin
• Is Part Of: Physical chemistry chemical physics. Volume 18:Issue 25(2016)
• Page Start: 16856
• Page End: 16861
• Publication Date: 2016-06-10
• Subjects: Chemistry, Physical and theoretical -- Periodicals; 541.3
• DOI: 10.1039/c6cp02654k
• Languages: English
• ISSNs: 1463-9076

Abstract

Abstract : Glassy metallic alloys are richly tunable model systems for surface glassy dynamics. Abstract : Glassy metallic alloys are richly tunable model systems for surface glassy dynamics. Here we study the correlation between atomic mobility, and the hopping rate of surface regions (clusters) that rearrange collectively on a minute to hour time scale. Increasing the proportion of low-mobility copper atoms in La–Ni–Al–Cu alloys reduces the cluster hopping rate, thus establishing a microscopic connection between atomic mobility and dynamics of collective rearrangements at a glass surface made from freshly exposed bulk glass. One composition, La60 Ni15 Al15 Cu10, has a surface resistant to re-crystallization after three heating cycles. When thermally cycled, surface clusters grow in size from about 5 glass-forming units to about 8 glass-forming units, evidence of surface aging without crystal formation, although its bulk clearly forms larger crystalline domains. Such kinetically stable glass surfaces may be of use in applications where glassy coatings stable against heating are needed.