Titanium oxo-clusters derivatized from the Ti10O12(cat)8(py)8 complex: structural investigation and spectroscopic studies of light absorption. Issue 21 (4th May 2016)

• Record Type: Journal Article
• Authors: Chaumont, Clément; Chaumont, Alain; Kyritsakas, Nathalie; Mobian, Pierre; Henry, Marc
• Is Part Of: Dalton transactions. Volume 45:Issue 21(2016)
• Page Start: 8760
• Page End: 8769
• Publication Date: 2016-05-04
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt00632a
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : Three deep-red catecholato-based titanium oxo-clusters are obtained from the Ti10 O12 (cat)8 (py)8 (py = pyridine) complex. Calculations enable us to assign the electronic transitions responsible for the visible light absorption and highlight that pyridine ligands influence the density of states plot. Abstract : A series of deep-red colored nano-sized titanium oxo-clusters bearing catecholato ligands is reported. These architectures are produced via post-synthetic modification of the Ti10 O12 (cat)8 (py)8 (cat = catecholato, py = pyridine) complex through quantitative substitution of labile pyridine ligands by three substituted pyridines (pico, 4-Phpy and pyrald). The crystal structure analysis reveals a common Ti10 O12 (cat)8 backbone for the three isolated molecular architectures. Partial charge analysis indicates two types of titanium atoms within these complexes with one resembling titanium(iv ) found in TiO2 . These complexes strongly absorb visible light in solution ( λ max = 411 nm, ε = 10 800 for Ti10 O12 (cat)8 (py)8 in CHCl3 ) and in the solid-state. The band gaps estimated from the reflectance spectra are between 1.85 eV and 1.97 eV. The present work also details the HOMO and LUMO representations obtained via DFT calculation for Ti10 O12 (cat)8 (py)8 and a virtual Ti10 O12 (cat)8 complex as well as the DOS (density of states) plots calculated for those structures. This computational study highlights an impact of the pyridine ligand on the DOS plots.