A three-dimensional porous MoP@C hybrid as a high-capacity, long-cycle life anode material for lithium-ion batteries. Issue 19 (3rd May 2016)

• Record Type: Journal Article
• Authors: Wang, Xia; Sun, Pingping; Qin, Jinwen; Wang, Jianqiang; Xiao, Ying; Cao, Minhua
• Is Part Of: Nanoscale. Volume 8:Issue 19(2016)
• Page Start: 10330
• Page End: 10338
• Publication Date: 2016-05-03
• Subjects: Nanoscience -- Periodicals; Nanotechnology -- Periodicals; 620.505
• DOI: 10.1039/c6nr01774f
• Languages: English
• ISSNs: 2040-3364

Abstract

Abstract : We demonstrate a versatile strategy for the synthesis of a novel three-dimensional porous molybdenum phosphide@carbon hybrid, which shows excellent lithium storage performance. Abstract : Metal phosphides are great promising anode materials for lithium-ion batteries with a high gravimetric capacity. However, significant challenges such as low capacity, fast capacity fading and poor cycle stability must be addressed for their practical applications. Herein, we demonstrate a versatile strategy for the synthesis of a novel three-dimensional porous molybdenum phosphide@carbon hybrid (3D porous MoP@C hybrid) by a template sol–gel method followed by an annealing treatment. The resultant hybrid exhibits a 3D interconnected ordered porous structure with a relatively high surface area. Benefiting from its advantages of microstructure and composition, the 3D porous MoP@C hybrid displays excellent lithium storage performance as an anode material for lithium-ion batteries in terms of specific capacity, cycling stability and long-cycle life. It presents stable cycling performance with a high reversible capacity up to 1028 mA h g −1 at a current density of 100 mA g −1 after 100 cycles. By ex situ XRD, HRTEM, SAED and XPS analyses, the 3D porous MoP@C hybrid was found to follow the Li-intercalation reaction mechanism (MoP + x Li + + e − ↔ Li x MoP), which was further confirmed by ab initio calculations based on density functional theory.