2, 3-Dichloro-5, 6-dicyano-1, 4-benzoquinone-catalyzed aerobic oxidation reactions via multistep electron transfers with iron(ii) phthalocyanine as an electron-transfer mediator. Issue 57 (27th May 2016)

• Record Type: Journal Article
• Authors: Hong, Yiming; Fang, Tiantian; Li, Meichao; Shen, Zhenlu; Hu, Xinquan; Mo, Weimin; Hu, Baoxiang; Sun, Nan; Jin, Liqun
• Is Part Of: RSC advances. Volume 6:Issue 57(2016)
• Page Start: 51908
• Page End: 51913
• Publication Date: 2016-05-27
• Subjects: Chemistry -- Periodicals; 540.5
• DOI: 10.1039/c6ra08921f
• Languages: English
• ISSNs: 2046-2069

Abstract

Abstract : A new biomimetic catalytic oxidation system was developed for oxidative deprotection of PMB ethers, alcohol oxidation, aromatization and α, β-unsaturated aldehyde formation. Abstract : A new biomimetic catalytic oxidation system which employs 2, 3-dichloro-5, 6-dicyano-1, 4-benzoquinone (DDQ) as the catalyst, molecular oxygen as the terminal oxidant and iron(ii ) phthalocyanine (Fe II Pc) as the electron-transfer mediator has been developed. This system can be applied for oxidative deprotection of PMB ethers, alcohol oxidation, aromatization and α, β-unsaturated aldehyde formation. After immobilizing Fe II Pc on multi-walled carbon nanotubes, it can be reused without loss of activity.