Dye colour switching by hydride-terminated silicon particles and its application as an oxygen indicator. Issue 20 (22nd April 2016)

• Record Type: Journal Article
• Authors: Ye, Miaomiao; Qian, Chenxi; Sun, Wei; He, Le; Jia, Jia; Dong, Yuchan; Zhou, Wenjie
• Is Part Of: Journal of materials chemistry. Volume 4:Issue 20(2016)
• Page Start: 4577
• Page End: 4583
• Publication Date: 2016-04-22
• Subjects: Materials -- Periodicals; Chemistry, Analytic -- Periodicals; Optical materials -- Research -- Periodicals; Electronics -- Materials -- Research -- Periodicals; 543.0284
• DOI: 10.1039/c6tc00749j
• Languages: English
• ISSNs: 2050-7526

Abstract

Abstract : Redox dyes can be rapidly decolorized by hydride-terminated silicon particles and their original colors recovered when exposed to an oxygen environment. With this knowledge, a polymer–dye-based film was assembled and shown to function as an oxygen indicator. Abstract : While various forms of silicon have been widely used in the semiconductor industry and other fields, this is the first time hydride-terminated silicon particles have been employed as a reducing agent for redox active dyes. The vivid colours of the dyes can be easily decoloured within seconds to minutes by hydride-terminated silicon particles with different sizes in the nanometer to micron size range and completely recovered to their original colours after separating the silicon particles and further exposing to air. As a comparison, other traditional reducing agents such as Na2 SO3 and NaBH4, as well as the silicon particles without HF etching were also employed for the reduction–reoxidation of the dye, respectively. By making use of the colour switching property of the dye, a polymer–dye composite film was shown to function as an indicator for oxygen. This film is very sensitive to oxygen and air while remaining stable in vacuum, argon, carbon dioxide and nitrogen gas atmospheres. Oxygen indicator films with different colours can also be made by incorporating different redox active dyes in the films.