CeO2‐Catalyzed C‐H Functionalization of N‐Aryltetrahydroisoquinolines: An Aerobic Cross‐Dehydrogenative Coupling Reaction between Two sp3 C‐H Bonds. Issue 15 (22nd September 2016)

• Record Type: Journal Article
• Authors: Sharma, Kumud; Borah, Ashwini; Neog, Kashmiri; Gogoi, Dr Pranjal
• Is Part Of: ChemistrySelect. Volume 1:Issue 15(2016)
• Page Start: 4620
• Page End: 4623
• Publication Date: 2016-09-22
• Subjects: Carbon-Carbon bond formation -- CDC -- Ceria -- Heterogeneous catalyst -- Tetrahydroisoquinoline; Chemistry -- Periodicals; 540.5
• DOI: 10.1002/slct.201601251
• Languages: English
• ISSNs: 2365-6549

Abstract

Abstract: CeO2 has been used as heterogeneous catalyst for carbon‐carbon bond formation via cross‐dehydrogenative coupling (CDC). It works efficiently for oxidative C−C bond formation between N ‐aryltetrahydroisoquinoline derivatives and a carbon nucleophile nitroalkane and acetone under aerobic conditions. This is the first report of CeO2 as a low temperature catalyst for the carbon‐carbon bond formation reaction between two sp3 C−H bonds. Abstract : CeO2 has been used as heterogeneous catalyst for carbon‐carbon bond formation via cross‐dehydrogenative coupling (CDC). It works efficiently for oxidative C−C bond formation between N ‐aryltetrahydroisoquinoline derivatives and a carbon nucleophile nitroalkane and acetone under air. This is the first report of CeO2 as a low temperature catalyst for the carbon‐carbon bond formation reaction between two sp 3 C−H bonds.