Ionothermal Synthesis of Lanthanide Tetrafluoride Nanoparticles Using Deep Eutectic Solvents. Issue 1804 (2015)

• Record Type: Journal Article
• Authors: Furman, Benjamin R.; Gutierrez, Robert D.; Baker, Charles K.
• Editors: Shukla, P.; Kato, K.; Obradors, X.; Mathur, S.
• Is Part Of: MRS proceedings. Issue 1804(2015)
• Page Start: 25
• Page End: 30
• Publication Date: 2015
• Subjects: nucleation & growth, -- particulate, -- optical properties; Electrical engineering -- Congresses; Physics -- Congresses; Materials -- Research -- Congresses; Materials science -- Congresses; 620.11
• DOI: 10.1557/opl.2015.532
• Languages: English
• ISSNs: 0272-9172

Abstract

ABSTRACT: We have developed a new method for controlling the size, crystallinity, and polydispersity of 100–2000 nm tetrafluoride phosphor particles. Five polyol-based deep eutectic solvents (DESs) were downselected out of a set of more than 130 candidates. We analyzed their benefits in synthesizing phosphor matrix particles of β -NaYF4, β -NaYbF4, and β -NaGdF4 . We produced green (λmax = 540 nm) and blue/UV (λmax = 450 nm) upconverting phosphors in DES using Yb, Er and Yb, Tm codopants, respectively. The blue/UV phosphor reaction was scaled the up to 25 L, yielding nearly 400 g of high-quality, bright photoluminescent, β -phase product under mild conditions. We conclude that polyol-based DES systems offer a uniquely specialized and useful toolkit for phosphor synthesis.