Trimeric hexa-dimethyltin-functionalized selenotungstate [{Sn(CH3)2(CH3COO)}3{Sn(CH3)2}3{Se2W18O62(OH)(H2O)}3]18−. Issue 16 (31st March 2016)

• Record Type: Journal Article
• Authors: Chen, Wei-Chao; Qin, Chao; Wang, Xin-Long; Wu, Cai-Xia; Li, Yang-Guang; Zang, Hong-Ying; Shao, Kui-Zhan; Su, Zhong-Min; Wang, En-Bo
• Is Part Of: CrystEngComm. Volume 18:Issue 16(2016)
• Page Start: 2820
• Page End: 2824
• Publication Date: 2016-03-31
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c6ce00377j
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : The trimeric hybrid organic–inorganic selenotungstate(iv ) [{Sn(CH3 )2 (CH3 COO)}3 {Sn(CH3 )2 }3 {Se2 W18 O62 (OH)(H2 O)}3 ] 18− involving the first reported carboxyl-modified dimethyltin moieties exhibits photocatalytic H2 evolution activity. Abstract : The trimeric organic–inorganic hybrid selenotungstate(iv ) [{Sn(CH3 )2 (CH3 COO)}3 {Sn(CH3 )2 }3 {Se2 W18 O62 (OH)(H2 O)}3 ] 18− is composed of three Wells–Dawson-type {α-Se2 W18 } fragments and six {(CH3 )2 Sn 2+ } groups involving the first reported carboxyl-modified dimethyltin moieties, exhibiting photocatalytic H2 evolution activity.