Oxidation State Dependent Coordination Modes: Accessing an Amidate‐Supported Nickel(I) δ‐bis(C−H) Agostic Complex. (6th October 2016)

• Record Type: Journal Article
• Authors: Beattie, D. Dawson; Bowes, Eric G.; Drover, Marcus W.; Love, Jennifer A.; Schafer, Laurel L.
• Is Part Of: Angewandte Chemie. Volume 128:Number 42(2016)
• Page Start: 13484
• Page End: 13489
• Publication Date: 2016-10-06
• Subjects: Agostische Komplexe -- AIM-Rechnungen -- Amidate -- Nickel -- Redoxzustände; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201607243
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: Amidate‐supported two‐ and three‐coordinate Ni I complexes were synthesized by reduction of the corresponding Ni II precursors. A dramatic change in binding mode is observed upon reduction from Ni II to Ni I . The Ni I derivatives include an unprecedented Ni I bis(C−H) agostic complex and a two‐coordinate Ni I complex.