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ChemInform Abstract: Enantio‐ and Diastereoselective Desymmetrization of α‐Alkyl‐α‐diazoesters by Dirhodium(II)‐Catalyzed Intramolecular C—H Insertion. Issue 43 (7th October 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Enantio‐ and Diastereoselective Desymmetrization of α‐Alkyl‐α‐diazoesters by Dirhodium(II)‐Catalyzed Intramolecular C—H Insertion. Issue 43 (7th October 2016)
Main Title:
ChemInform Abstract: Enantio‐ and Diastereoselective Desymmetrization of α‐Alkyl‐α‐diazoesters by Dirhodium(II)‐Catalyzed Intramolecular C—H Insertion.
Abstract: The title reaction proceeds best in the presence of the Rh catalyst shown to form bicyclic ring systems with at least one cyclopentane unit in an enantio‐ and diastereoselective manner.