ChemInform Abstract: Umpolung Synthesis of Diarylmethylamines via Palladium‐Catalyzed Arylation of N‐Benzyl Aldimines. Issue 43 (7th October 2016)

• Record Type: Journal Article
• Authors: Li, Minyan; Yucel, Baris; Jimenez, Jacqueline; Rotella, Madeline; Fu, Yue; Walsh, Patrick J.
• Is Part Of: ChemInform. Volume 47:Issue 43(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-10-07
• Subjects: polyphenylalkane derivatives -- C‐C bond formation -- amines (benzene compounds); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201643092
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: The arylation of unsymmetrical aldimines (IV) and (VI) proceeds regioselectively at the sterically less hindered position leading to imines (V) and (VII), whilst the reaction of aldimine (VIII) affords a mixture of isomers (IX) and (X).