Chain Entanglements and Hydrogen Bonds in Carbopol Microgel Reinforced Hydrogel. Issue 19 (25th August 2016)

• Record Type: Journal Article
• Authors: Zhang, Xiuyin; Zhao, Chuanzhuang; Xiang, Nanping; Li, Wei
• Is Part Of: Macromolecular chemistry and physics. Volume 217:Issue 19(2016:Oct.)
• Page Start: 2139
• Page End: 2144
• Publication Date: 2016-08-25
• Subjects: hydrogels -- hydrogen bonds -- interpenetrating networks -- microgels; Polymers -- Periodicals; Polymerization -- Periodicals; Synthetic products -- Periodicals; Macromolecules -- Periodicals; 547.7
• DOI: 10.1002/macp.201600245
• Languages: English
• ISSNs: 1022-1352

Abstract

Abstract : Physical interaction between the microgel and the hydrogel matrix is a key issue in the rational design of microgel reinforced hydrogels. A pentaerythritol‐crosslinked poly(acrylic acid) (PAAc) microgel, named Carbopol, is composited with polyacrylamide (PAAm) hydrogel. The toughness of the hydrogel is significantly improved by constructing an interpenetrating network of Carbopol and PAAm. Chain entanglements within the composited hydrogel result in a strain‐hardening phenomenon and an efficient stress transfer from the PAAm matrix to the sacrificing network of Carbopol. Hydrogen bonds between PAAc and PAAm can be formed in an acidic environment, which function as reversible sacrificing bonds and further improve the stretchability of the hydrogel. Abstract : Carbopol microgel is used to reinforce polyacrylamide hydrogel. Chain entanglements transfer the mechanical energy from the hydrogel to the microgel. Cooperative hydrogen bonds function as reversible sacrificing bonds, further enhancing the toughness of the hydrogel.