Synthesis and liquid crystalline behaviour of substituted (E)-phenyl-4-(phenyldiazenyl) benzoate derivatives and their photo switching ability. Issue 11 (1st September 2016)

• Record Type: Journal Article
• Authors: Hegde, Gurumurthy; Shanker, Govindaswamy; Gan, S. M.; Yuvaraj, A. R.; Mahmood, Syed; Mandal, Uttam Kumar
• Is Part Of: Liquid crystals. Volume 43:Issue 11(2016)
• Page Start: 1578
• Page End: 1588
• Publication Date: 2016-09-01
• Subjects: Photoisomerisation -- azobenzene derivatives -- liquid crystals -- storage device -- thermal back relaxation -- photolock; Liquid crystals -- Periodicals; 548.905
• DOI: 10.1080/02678292.2016.1189001
• Languages: English
• ISSNs: 0267-8292

Abstract

ABSTRACT: Azobenzene derivatives containing phenyl/4-halogen-phenyl 4-{(E)-[4-(pent-4-en-1-yloxy)phenyl]diazenyl}benzoate group with different electronegative substituent (H, F, Cl, Br and I) at other end was synthesised. These azo-based benzoate derivatives have been characterised by FTIR, 1 H-NMR, 13 C-NMR, elemental analyser, POM and UV-Vis spectroscopy. Photosaturation at 358 nm obtained after 82 s of UV irradiation and the longest thermal back relaxation time of 45 h recorded by UV-Vis. The azo derivative could be possible photolock under UV light, as observed by the improved thermal back relaxation time. The resulting photolockable chain of azobenzene might prove valuable in the development of optical device application. These azobenzene moieties also exhibit liquid crystalline behaviour with respect to the halogen substitution as an electron withdrawing group shows that strong structure property relationship exists among them. GRAPHICAL ABSTRACT: