A Bis(silylene)‐Substituted ortho‐Carborane as a Superior Ligand in the Nickel‐Catalyzed Amination of Arenes. (15th September 2016)

• Record Type: Journal Article
• Authors: Zhou, Yu‐Peng; Raoufmoghaddam, Saeed; Szilvási, Tibor; Driess, Matthias
• Is Part Of: Angewandte Chemie. Volume 128:Number 41(2016)
• Page Start: 13060
• Page End: 13064
• Publication Date: 2016-09-15
• Subjects: Homogene Katalyse -- N-heterocyclische Silylene -- Ligandenentwicklung -- Nickel -- o-Carborane; Chemistry -- Periodicals; 540
• DOI: 10.1002/ange.201606979
• Languages: English
• ISSNs: 0044-8249

Abstract

Abstract: The synthesis and structure of the first 1, 2‐bis(NHSi)‐substituted ortho ‐carborane [(LSi:)C]2 B10 H10 (termed SiCCSi) is reported (NHSi= N ‐heterocyclic silylene; L=PhC(NtBu)2 ). Its suitability to serve as a reliable bis(silylene) chelating ligand for transition metals is demonstrated by the formation of [SiCCSi]NiBr2 and [SiCCSi]Ni(CO)2 complexes. The CO stretching vibration modes of the latter indicate that the Si II atoms in the SiCCSi ligand are even stronger σ donors than the P III atoms in phosphines and C II atoms in N ‐heterocyclic carbene (NHC) ligands. Moreover, the strong donor character of the [SiCCSi] ligand enables [SiCCSi]NiBr2 to act as an outstanding precatalyst (0.5 mol % loading) in the catalytic aminations of arenes, surpassing the activity of previously known molecular Ni‐based precatalysts (1–10 mol %).