Synthesis of Ion Imprinted Polymers by Copolymerization of Zn(II) and Al(III)8-hydroxy Quinolone Complexes with Divinylbenzene and Methacryclic Acid. (21st September 2016)

• Record Type: Journal Article
• Authors: Ara, Behisht; Muhammad, Mian; Amin, Hira; , Noori; Begum, Robina; Jabeen, Salma; Gul, Sana; Zia, Tanveer ul Haq; Nasir, Habib
• Is Part Of: Polymer-plastics technology and engineering. Volume 55:Number 14(2016)
• Page Start: 1460
• Page End: 1473
• Publication Date: 2016-09-21
• Subjects: Al(III) -- copolymerization -- divinylbenzene -- 8-hydroxyquinoline -- ion imprinted polymer -- methacrylic acid -- Zn(II); Polymers -- Periodicals; Polymerization -- Periodicals; Polymers -- Periodicals; Engineering -- Periodicals; Plastics -- Periodicals; 668.9
• DOI: 10.1080/03602559.2015.1132462
• Languages: English
• ISSNs: 0360-2559

Abstract

ABSTRACT: In this research work, Zinc(II) and Aluminum(III)-IIP's were synthesized by optimizing the amount of methacrylic acid as monomer, divinylbenzene as cross-linker. The IIP's were functionalized with 8-hydroxy quinolone complexes of the two metal ions under thermal conditions by copolymerization with monomer and cross-linker. The IIP's and Non-IIP's were characterized using FT-IR, TGA, and SEM analysis. A quite remarkable difference in the size was observed of the polymers (Zn(II) 1.0 µm and Al(III) 0.1 µm). A stronger affinity was observed with IIP in comparison with Non-IIP at pH 3.1 and 4.5 for Zn(II) and Al(III) ions on their respective polymers. GRAPHICAL ABSTRACT: