DBN hexafluorophosphate salts as convenient sulfonylating and phosphonylating agents. Issue 36 (30th August 2016)

• Record Type: Journal Article
• Authors: Jones, Caroline S.; Bull, Steven D.; Williams, Jonathan M. J.
• Is Part Of: Organic & biomolecular chemistry. Volume 14:Issue 36(2016)
• Page Start: 8452
• Page End: 8456
• Publication Date: 2016-08-30
• Subjects: Chemistry, Organic -- Periodicals; Bioorganic chemistry -- Periodicals; Chemistry, Physical organic -- Periodicals; 547
• DOI: 10.1039/c6ob01854h
• Languages: English
• ISSNs: 1477-0520

Abstract

Abstract : Air-stable N -sulfonyl and N -phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. Abstract : Air-stable N -sulfonyl and N -phosphonyl DBN hexafluorophosphate salts have been synthesised under mild conditions as sulfonylating and phosphonylating agents. These salts are highly efficient in the sulfonylation and phosphonylation of a range of N - and O -nucleophiles to generate sulfonamides, sulfonate esters, phosphoramidates and phosphonate esters in good yields.