A four-fold interpenetrated metal–organic framework as a fluorescent sensor for volatile organic compounds. Issue 38 (18th August 2016)

• Record Type: Journal Article
• Authors: Zhao, Xiaoyu; Li, Yang; Chang, Ze; Chen, Long; Bu, Xian-He
• Is Part Of: Dalton transactions. Volume 45:Issue 38(2016)
• Page Start: 14888
• Page End: 14892
• Publication Date: 2016-08-18
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt02169g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : A highly luminescent four-fold interpenetrated 3D metal–organic framework based on an AIE active tetrakis(4-(pyridin-4-yl)phenyl)ethene ligand was facilely synthesized and thoroughly investigated. Abstract : A four-fold interpenetrated three dimensional (3D) metal–organic framework, [Cd2 (tppe)(bpdc)2 (H2 O)]·solvent (1 ), was synthesized with a tetraphenylethene (TPE)-based ligand, 1, 1, 2, 2-tetrakis(4-(pyridin-4-yl)phenyl)ethene (TPPE). This complex exhibits intense blue luminescence and is sensitive to toxic volatile organic compounds (VOCs).