Iron-catalyzed clean dehydrogenative coupling of alcohols with P(O)–H compounds: a new protocol for ROH phosphorylation. Issue 38 (1st September 2016)

• Record Type: Journal Article
• Authors: Li, Chunya; Chen, Tieqiao; Han, Li-Biao
• Is Part Of: Dalton transactions. Volume 45:Issue 38(2016)
• Page Start: 14893
• Page End: 14897
• Publication Date: 2016-09-01
• Subjects: Chemistry, Inorganic -- Periodicals; Chemistry, Physical and theoretical -- Periodicals; Chemistry, Inorganic -- Periodicals; 546.05
• DOI: 10.1039/c6dt02236g
• Languages: English
• ISSNs: 1477-9226

Abstract

Abstract : An efficient oxygen–phosphoryl bond-forming reaction via iron-catalyzed cross dehydrogenative coupling has been developed. The reaction proceeds efficiently under oxidant- and halide-free conditions with H2 liberation, and represents a straightforward method to prepare organophosphoryl compounds from alcohols and P(O)–H compounds. Abstract : An efficient oxygen–phosphoryl bond-forming reaction via iron-catalyzed cross dehydrogenative coupling has been developed. This transformation proceeds efficiently under oxidant- and halide-free reaction conditions with H2 liberation, and represents a straightforward method to prepare valuable organophosphoryl compounds from the readily available alcohols and P(O)–H compounds.