Layer-structured coordination polymers based on 5-(1H-tetrazol-5-yl)isophthalic acid: structure, sensitization of lanthanide(iii) cations and small-molecule sensing. Issue 37 (30th August 2016)

• Record Type: Journal Article
• Authors: Jia, Jia; Xu, Jianing; Wang, Shengyan; Wang, Pengcheng; Gao, Lijuan; Chai, Juan; Shen, Lanlan; Chen, Xiaobo; Fan, Yong; Wang, Li
• Is Part Of: CrystEngComm. Volume 18:Issue 37(2016)
• Page Start: 7126
• Page End: 7134
• Publication Date: 2016-08-30
• Subjects: Crystals -- Periodicals; Crystal growth -- Periodicals; Crystallography -- Periodicals; Cristaux -- Périodiques; Cristaux -- Croissance -- Périodiques; Cristallographie -- Périodiques; 548
• DOI: 10.1039/c6ce00883f
• Languages: English
• ISSNs: 1466-8033

Abstract

Abstract : Compound1 can serve as a host for encapsulation of Ln 3+ ions. Abstract : Three layer-structured coordination polymers (CPs), namely, [Pb2 (TZI)(μ3 -OH)(H2 O)·(H2 O)] n (1 ), [Pb(HTZI)(phen)·(H2 O)] n (2 ) and [Zn2 (TZI)(μ3 -OH)(H2 O)2 ·(1/2H2 O)] n (3 ) have been constructed from the 5-(1 H -tetrazol-5-yl)isophthalic acid (H3 TZI) ligand. Notably, 1 can function as a host for the encapsulation of lanthanide(iii ) ions by encapsulating different Ln 3+ ions. As-prepared Ln 3+ @1 materials show tunable luminescent emission including white-light emission. Moreover, 1 exhibits highly luminescent sensing properties for small organic molecules.