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Dual structure evolution of a Ag(i) supramolecular framework triggered by anion-exchange: replacement of terminal ligand and switching of network interpenetration degree12. Issue 74 (25th August 2016)
Record Type:
Journal Article
Title:
Dual structure evolution of a Ag(i) supramolecular framework triggered by anion-exchange: replacement of terminal ligand and switching of network interpenetration degree12. Issue 74 (25th August 2016)
Main Title:
Dual structure evolution of a Ag(i) supramolecular framework triggered by anion-exchange: replacement of terminal ligand and switching of network interpenetration degree12
Abstract : Dual single-crystal to single-crystal transformations triggered by different anion-exchanges are achieved for a Ag(i ) coordination framework, where switching of network interpenetration degree is observed. Abstract : A 3-fold interpenetrated Ag(i ) coordination framework can exhibit dual structure evolution behaviours driven by distinct anion-exchange courses in which irreversible single-crystal to single-crystal transformation occurs, resulting in a switching of network interpenetration degree (from 3-fold to 2-fold).