Enhancing the magnetic blocking temperature and magnetic coercivity of {CrIII2LnIII2} single-molecule magnets via bridging ligand modification. Issue 73 (17th August 2016)

• Record Type: Journal Article
• Authors: Langley, Stuart K.; Wielechowski, Daniel P.; Moubaraki, Boujemaa; Murray, Keith S.
• Is Part Of: Chemical communications. Volume 52:Issue 73(2016)
• Page Start: 10976
• Page End: 10979
• Publication Date: 2016-08-17
• Subjects: Chemistry -- Periodicals; 540
• DOI: 10.1039/c6cc06152d
• Languages: English
• ISSNs: 1359-7345

Abstract

Abstract : Replacing bridging benzoate ligands with 2-chloro-4, 5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets results in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity. Abstract : Replacing bridging benzoate ligands with 2-chloro-4, 5-fluorobenzoate in a family of {CrIII2LnIII2} (Ln = Tb, Dy and Ho) single-molecule magnets result in significant improvements in magnetic relaxation time, magnetic hysteresis blocking temperature and magnetic coercivity.