Cobalt‐Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity. (1st August 2016)
- Record Type:
- Journal Article
- Title:
- Cobalt‐Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity. (1st August 2016)
- Main Title:
- Cobalt‐Catalyzed Alkyne Hydrosilylation and Sequential Vinylsilane Hydroboration with Markovnikov Selectivity
- Authors:
- Zuo, Ziqing
Yang, Ji
Huang, Zheng - Abstract:
- Abstract: A pyridinebis(oxazoline) cobalt complex is a very efficient precatalyst for the hydrosilylation of terminal alkynes with Ph2 SiH2, providing α‐vinylsilanes with high (Markovnikov) regioselectivity and broad functional‐group tolerance. The vinylsilane products can be further converted into geminal borosilanes through Markovnikov hydroboration with pinacolborane and a bis(imino)pyridine cobalt catalyst.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 36(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 36(2016)
- Issue Display:
- Volume 128, Issue 36 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 36
- Issue Sort Value:
- 2016-0128-0036-0000
- Page Start:
- 10997
- Page End:
- 11001
- Publication Date:
- 2016-08-01
- Subjects:
- Alkine -- Cobalt -- Hydroborierungen -- Hydrosilylierungen -- Vinylsilane
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201605615 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1446.xml