ChemInform Abstract: High‐Pressure Control of Vanadium Self‐Intercalation and Enhanced Metallic Properties in 1T‐V1+xS2 Single Crystals. Issue 36 (August 2016)

• Record Type: Journal Article
• Authors: Moutaabbid, Hicham; Le Godec, Yann; Taverna, Dario; Baptiste, Benoit; Klein, Yannick; Loupias, Genevieve; Gauzzi, Andrea
• Is Part Of: ChemInform. Volume 47:Issue 36(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-08
• Subjects: vanadium, V -- sulfur, S -- structure (solids and liquids); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201636012
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: High‐quality 1T‐V1+x S2 (x = 0.09—0.17) single crystals with self‐intercalated V atoms in the van der Waals gap of the layered host are prepared by first reacting a 1:2.1 molar mixture of V and S to achieve single crystalline V5 S8 (750 °C, 3 weeks) followed by reaction with 2.05 equivs.