ChemInform Abstract: 2, 2, 2‐Trifluoroethyl Oxalates in the One‐Pot Parallel Synthesis of Hindered Aliphatic Oxamides. Issue 36 (August 2016)

• Record Type: Journal Article
• Authors: Moroz, Yurii S.; et al.,
• Is Part Of: ChemInform. Volume 47:Issue 36(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-08
• Subjects: carboxylic amides (acyclic compounds) -- amide formation -- multicomponent reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201636057
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: Unsymmetrical N 1, N 2 ‐substituted aliphatic oxamides (52 examples) are prepared by stepwise aminolysis of methyl(trifluoroethyl)oxalate or bis(trifluoroethyl)oxalate with hindered primary and secondary aliphatic amines, resp., in moderate yields.