ChemInform Abstract: Palladium‐Catalyzed Arylation of β‐Methylene C(sp3)—H Bonds at Room Temperature: Desymmetrization of Simple Cycloalkyl Carboxylic Acids. Issue 37 (August 2016)

• Record Type: Journal Article
• Authors: Nack, W. A.; Wang, B.; Wu, X.; Jiao, R.; He, G.; Chen, G.
• Is Part Of: ChemInform. Volume 47:Issue 37(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-08
• Subjects: C‐C bond formation -- general (alicyclic compounds) -- carboxylic amides (acyclic compounds) -- diastereoselective syntheses, enantioselective syntheses (incl. cis/trans‐isomerism); Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201637032
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: In most cases, the β methylene C—H bonds of cycloalkylcarboxamides of varied ring size are monoarylated giving products with excellent cis‐diastereoselectivity whereby, diarylated products are also observed as by‐products.