ChemInform Abstract: An Efficient Synthesis of α‐Isothiocyanato‐α, β‐unsaturated Esters from Morita—Baylis—Hillman Adducts. Issue 38 (September 2016) - Kim, Ko Hoon
Abstract: A facile one‐pot method for the synthesis of the title esters is developed involving the dehydration of the nitroalkane side‐chain of Morita—Baylis—Hillman adducts generating the corresponding nitrile oxide, and the following [3+2] cycloaddition to the C=S bond of thiourea affording a diaminooxathiazole intermediate.