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ChemInform Abstract: Controlled TfOH‐ or AuCl‐Catalyzed Cycloisomerization and Tandem Hydrolytic Defluorination of 1, 2‐Allenyl Perfluoroalkyl Ketones. Issue 38 (September 2016)
Record Type:
Journal Article
Title:
ChemInform Abstract: Controlled TfOH‐ or AuCl‐Catalyzed Cycloisomerization and Tandem Hydrolytic Defluorination of 1, 2‐Allenyl Perfluoroalkyl Ketones. Issue 38 (September 2016)
Main Title:
ChemInform Abstract: Controlled TfOH‐ or AuCl‐Catalyzed Cycloisomerization and Tandem Hydrolytic Defluorination of 1, 2‐Allenyl Perfluoroalkyl Ketones.
Abstract: An efficient cycloisomerization of allenyl perfluoroalkyl ketones under the catalysis of gold(I) chloride (for trisubstituted allenones) or triflic acid (for fully substituted allenones) is described.