ChemInform Abstract: Gold‐Catalyzed Aminoalkenylation of β‐Amino‐1, n‐diynols to Cycloalkyl‐, Piperidinyl‐ and Pyranyl‐Fused Pyrroles. Issue 38 (September 2016)

• Record Type: Journal Article
• Authors: Kothandaraman, Prasath; Zhao, Yichao; Lee, Bo Ra; Le Ng, Clarrisa Jia; Lee, Jun Yi; Ayers, Benjamin James; Chan, Philip Wai Hong
• Is Part Of: ChemInform. Volume 47:Issue 38(2016)
• Page Start: no
• Page End: no
• Publication Date: 2016-09
• Subjects: fused pyrrole derivatives -- fused pyridine derivatives -- pyran derivatives -- ring closure reactions, annulation reactions -- catalysis, phase‐transfer catalysis -- cascade reactions, domino reactions, tandem reactions; Chemistry -- Abstracts -- Periodicals; 540.5
• DOI: 10.1002/chin.201638137
• Languages: English
• ISSNs: 0931-7597

Abstract

Abstract: A possible mechanistic pathway of the new synthetic approach for the synthesis of the title pyrroles involves a tandem C—N/C—C bond forming sequence and a gold‐mediated isomerization of the generated alkenylated intermediates.