Total Synthesis of the Diterpenoid (+)‐Harringtonolide. (16th August 2016)
- Record Type:
- Journal Article
- Title:
- Total Synthesis of the Diterpenoid (+)‐Harringtonolide. (16th August 2016)
- Main Title:
- Total Synthesis of the Diterpenoid (+)‐Harringtonolide
- Authors:
- Zhang, Hai‐Jun
Hu, Lin
Ma, Zhiqiang
Li, Ruining
Zhang, Zhen
Tao, Cheng
Cheng, Bin
Li, Yun
Wang, Huifei
Zhai, Hongbin - Abstract:
- Abstract: Described herein is the first asymmetric total synthesis of (+)‐harringtonolide, a natural diterpenoid with an unusual tropone imbedded in a cagelike framework. The key transformations include an intramolecular Diels–Alder reaction and a rhodium‐complex‐catalyzed intramolecular [3+2] cycloaddition to install the tetracyclic core as well as a highly efficient tropone formation.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 38(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 38(2016)
- Issue Display:
- Volume 128, Issue 38 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 38
- Issue Sort Value:
- 2016-0128-0038-0000
- Page Start:
- 11810
- Page End:
- 11813
- Publication Date:
- 2016-08-16
- Subjects:
- Asymmetrische Synthesen -- Cycloadditionen -- Naturstoffe -- Terpenoide -- Totalsynthesen
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201605879 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1775.xml