Asymmetric Hydrogenation of Azaindoles: Chemo‐ and Enantioselective Reduction of Fused Aromatic Ring Systems Consisting of Two Heteroarenes. (25th August 2016)
- Record Type:
- Journal Article
- Title:
- Asymmetric Hydrogenation of Azaindoles: Chemo‐ and Enantioselective Reduction of Fused Aromatic Ring Systems Consisting of Two Heteroarenes. (25th August 2016)
- Main Title:
- Asymmetric Hydrogenation of Azaindoles: Chemo‐ and Enantioselective Reduction of Fused Aromatic Ring Systems Consisting of Two Heteroarenes
- Authors:
- Makida, Yusuke
Saita, Masahiro
Kuramoto, Takahiro
Ishizuka, Kentaro
Kuwano, Ryoichi - Abstract:
- Abstract: High enantioselectivity was achieved for the hydrogenation of azaindoles by using the chiral catalyst, which was prepared from [Ru(η 3 ‐methallyl)2 (cod)] and a trans ‐chelating bis(phosphine) ligand (PhTRAP). The dearomative reaction exclusively occurred on the five‐membered ring, thus giving the corresponding azaindolines with up to 97:3 enantiomer ratio.
- Is Part Of:
- Angewandte Chemie. Volume 128:Number 39(2016)
- Journal:
- Angewandte Chemie
- Issue:
- Volume 128:Number 39(2016)
- Issue Display:
- Volume 128, Issue 39 (2016)
- Year:
- 2016
- Volume:
- 128
- Issue:
- 39
- Issue Sort Value:
- 2016-0128-0039-0000
- Page Start:
- 12038
- Page End:
- 12041
- Publication Date:
- 2016-08-25
- Subjects:
- Asymmetrische Katalyse -- Azaindole -- Chemoselektivität -- Hydrierungen -- Ruthenium
Chemistry -- Periodicals
540 - Journal URLs:
- http://onlinelibrary.wiley.com/ ↗
- DOI:
- 10.1002/ange.201606083 ↗
- Languages:
- English
- ISSNs:
- 0044-8249
- Deposit Type:
- Legaldeposit
- View Content:
- Available online (eLD content is only available in our Reading Rooms) ↗
- Physical Locations:
- British Library DSC - 0902.000000
British Library DSC - BLDSS-3PM
British Library HMNTS - ELD Digital store - Ingest File:
- 1297.xml